CobaltMaghrebV1, Main, Exploration, bibRecord, 000212

Poly[[diaquabis(μ2-4,4′-bipyridyl)cobalt(II)] dinitrate tetrahydrate]

Identifieur interne : 000212 ( Main/Exploration ); précédent : 000211; suivant : 000213

Poly[[diaquabis(μ2-4,4′-bipyridyl)cobalt(II)] dinitrate tetrahydrate]

Auteurs : Asma Lehleh [Algérie] ; Mehdi Boutebdja [Algérie] ; Adel Beghidja [Algérie] ; Chahrazed Beghidja [Algérie] ; Hocine Merazig [Algérie]

Source :

Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2013.

RBID : PMC:3629466

Abstract

The title compound, {[Co(C₁₀H₈N₂)₂(H₂O)₂](NO₃)₂·4H₂O}_n, (C₁₀H₈N₂ = 4,4′-bipyridine = 4,4′-bpy) is a layered coordination polymer built up from a cationic square grid extending in (101) enclosing uncoordinating nitrate ions and water molecules. The Co^II ion has site symmetry 2 and one of the 4,4′-bpy ligands is generated by twofold symmetry [two N atoms and two C atoms lie on the rotation axis and the dihedral angle between the pyridine rings is 45.66 (5)°]. The other 4,4′-bpy ligand is generated by a crystallographic inversion center. The Co^II ion exhibits a slightly distorted octahedral coordination geometry defined by two O atoms of two coordinating water molecules and four N atoms from four bridging 4,4′-bpy ligands. The structure is consolidated by O—H⋯O, C—H⋯O and C—H⋯N hydrogen bonds.

Url:

http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629466

DOI: 10.1107/S1600536813005230
PubMed: 23633984
PubMed Central: 3629466

Affiliations:

Algérie

Le document en format XML

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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main">Poly[[diaquabis(μ<sub>2</sub>
-4,4′-bipyridyl)cobalt(II)] dinitrate tetrahydrate]</title>
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<front><div type="abstract" xml:lang="en"><p>The title compound, {[Co(C<sub>10</sub>
H<sub>8</sub>
N<sub>2</sub>
)<sub>2</sub>
(H<sub>2</sub>
O)<sub>2</sub>
](NO<sub>3</sub>
)<sub>2</sub>
·4H<sub>2</sub>
O}<sub><italic>n</italic>
</sub>
, (C<sub>10</sub>
H<sub>8</sub>
N<sub>2</sub>
 = 4,4′-bipyridine = 4,4′-bpy) is a layered coordination polymer built up from a cationic square grid extending in (101) enclosing uncoordinating nitrate ions and water molecules. The Co<sup>II</sup>
 ion has site symmetry 2 and one of the 4,4′-bpy ligands is generated by twofold symmetry [two N atoms and two C atoms lie on the rotation axis and the dihedral angle between the pyridine rings is 45.66 (5)°]. The other 4,4′-bpy ligand is generated by a crystallographic inversion center. The Co<sup>II</sup>
 ion exhibits a slightly distorted octahedral coordination geometry defined by two O atoms of two coordinating water molecules and four N atoms from four bridging 4,4′-bpy ligands. The structure is consolidated by O—H⋯O, C—H⋯O and C—H⋯N hydrogen bonds.</p>
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Serveur d'exploration sur le cobalt au Maghreb

Poly[[diaquabis(μ2-4,4′-bipyridyl)cobalt(II)] dinitrate tetrahydrate]

Poly[[diaquabis(μ2-4,4′-bipyridyl)cobalt(II)] dinitrate tetrahydrate]

Source :

Abstract

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	Serveur d'exploration sur le cobalt au Maghreb
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Serveur d'exploration sur le cobalt au Maghreb

Poly[[diaqua­bis­(μ2-4,4′-bipyrid­yl)cobalt(II)] dinitrate tetra­hydrate]

Poly[[diaqua­bis­(μ2-4,4′-bipyrid­yl)cobalt(II)] dinitrate tetra­hydrate]

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Abstract

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Poly[[diaquabis(μ2-4,4′-bipyridyl)cobalt(II)] dinitrate tetrahydrate]

Poly[[diaquabis(μ2-4,4′-bipyridyl)cobalt(II)] dinitrate tetrahydrate]